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学科主题: 氟化学
题名: C-F Bond Cleavage by Intramolecular S(N)2 Reaction of Alkyl Fluorides with O- and N-Nucleophiles
其他题名: 利用氧-和氮-亲核试剂对烷基氟化物的SN2反应来实现C-F键断裂
作者: Zhang LJ(张来俊) ; Zhang W(张伟) ; Liu J(刘俊) ; Hu JB(胡金波)
通讯作者: 胡金波
刊名: J. Org. Chem.
发表日期: 2009
卷: 74, 期:7, 页:2850-2853
收录类别: SCI
部门归属: 上海有机所
英文摘要: The nucleophilic substitution of alkyl fluorides was achieved in the intramolecular reactions with O- and N-nucleophiles. The intramolecular defluorinative cyclization reaction was influenced by the nature of nucleophiles, the size of the ring to be formed, and the comformational rigidity of the precursors. Intermolecular nucleophilic substitution reactions of alkyl fluorides under similar reaction conditions were found to be difficult. The stereochemistry study of the current C-F bond cleavage reaction showed a complete configurational inversion, which supports an intramolecular S(N)2 reaction mechanism.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000264627400030
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/24049
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Zhang LJ,Zhang W,Liu J,et al. C-F Bond Cleavage by Intramolecular S(N)2 Reaction of Alkyl Fluorides with O- and N-Nucleophiles[J]. J. Org. Chem.,2009,74(7):2850-2853.
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