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学科主题: 氟化学
题名: N-Tosyl-S-difluoromethyl-S-phenylsulfoximine: A New Difluoromethylation Reagent for S-, N-, and C-Nucleophiles
其他题名: N-对甲苯磺酰-S-二氟甲基-S-苯基亚砜亚胺: 一种新的适用于硫-,氮-,碳-亲核试剂的二氟甲基化试剂
作者: Zhang W(张伟) ; Wang F(王飞) ; Hu JB(胡金波)
通讯作者: 胡金波
刊名: Org. Lett.
发表日期: 2009
卷: 11, 期:10, 页:2109-2112
收录类别: SCI
部门归属: 上海有机所
英文摘要: The first alpha-difluoromethyl sulfoximine compound, 2, was successfully prepared by using the copper(II)-catalyzed nitrene transfer reaction. Compound 2 was found to be a novel and efficient difluoromethylation reagent for transferring the CF2H group to S-, N-, and C-nucleophiles. Deuterium-labeling experiments suggest that a difluorocarbene mechanism is involved in the current difluoromethylation reactions.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000265908400017
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/24045
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Zhang W,Wang F,Hu JB. N-Tosyl-S-difluoromethyl-S-phenylsulfoximine: A New Difluoromethylation Reagent for S-, N-, and C-Nucleophiles[J]. Org. Lett.,2009,11(10):2109-2112.
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