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学科主题: 氟化学
题名: Fluoride ion-mediated nucleophilic fluoroalkylation of alkyl halides with Me3SiCF2SPh: Synthesis of PhSCF2- and CF2H-containing compounds
其他题名: Fluoride ion-mediated nucleophilic fluoroalkylation of alkyl halides with Me3SiCF2SPh: Synthesis of PhSCF2- and CF2H-containing compounds
作者: Li Y(李亚) ; Hu JB(胡金波)
通讯作者: 胡金波
刊名: J. Fluor. Chem.
发表日期: 2008-01-01
卷: 129, 期:5, 页:382-385
收录类别: SCI
部门归属: 中科院上海有机所
英文摘要: A facile and highly efficient nucleophilic (phenylthio)difluoromethylation of alkyl halides has been achieved via fluoride ion-mediated substitution reaction using [difluoro(phenylthio)methyl]trimethylsilane (Me3SiCF2SPh). The reaction proceeds well with primary alkyl bromides (or alkyl iodides) in DME solvent when CsF/15-crown-5 was used as the fluoride source/additive. The PhSCF2-containing products can be readily transformed into CF2H-containing compounds via a free-radical desulfurization method. (c) 2008 Elsevier B.V. All rights reserved.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/24039
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Li Y,Hu JB. Fluoride ion-mediated nucleophilic fluoroalkylation of alkyl halides with Me3SiCF2SPh: Synthesis of PhSCF2- and CF2H-containing compounds[J]. J. Fluor. Chem.,2008,129(5):382-385.
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