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学科主题: 氟化学
题名: Synthesis of 1,1-difluoroethylsilanes and their application for the introduction of the 1,1-difluoroethyl group
其他题名: 1,1-二氟乙基硅烷的合成及其在1,1-二氟乙基化反应中的应用
作者: Mogi, Ryo ; Morisaki, Kazuo ; Hu JB(胡金波) ; Prakash, Surya ; Olah, George A.
通讯作者: Prakash, Surya
刊名: J. Fluor. Chem.
发表日期: 2007-01-01
卷: 128, 期:10, 页:1098-1103
收录类别: SCI
部门归属: 日本关东电化公司; 中科院上海有机所; 南加州大学
英文摘要: 1,1-Difluoroethysilanes (R3SiCF2CH3, R=Me or Et) were synthesized from 1,1-difluoroethyl phenyl sulfone and chlorosilanes using magnesium metal via reductive 1,1-difluoroethylation. It was confirmed that 1,1-difluoroethylsilanes were effective 1,1-difluoroethylating reagents for carbonyl compounds. (C) 2007 Elsevier B.V. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000250619900005
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/24031
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Mogi, Ryo,Morisaki, Kazuo,Hu JB,et al. Synthesis of 1,1-difluoroethylsilanes and their application for the introduction of the 1,1-difluoroethyl group[J]. J. Fluor. Chem.,2007,128(10):1098-1103.
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