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学科主题: 氟化学
题名: Nucleophilic (phenylsulfinyl)difluoromethylation of carbonyl compounds with difluoromethyl phenyl sulfoxide
其他题名: 利用二氟甲基苯基亚砜对羰基化合物进行亲核苯亚磺酰二氟甲基化反应
作者: Zhu LG(朱林桂) ; Li Y(李亚) ; Ni CF(倪传法) ; Hu JB(胡金波) ; Beier, Petr ; Prakash, Surya ; Olah, George A.
通讯作者: 胡金波
刊名: J. Fluor. Chem.
发表日期: 2007
卷: 128, 期:10, 页:1241-1247
收录类别: SCI
部门归属: 中科院上海有机所; 南加州大学
英文摘要: We have successfully achieved nucleophilic (phenylsulfinyl)difluoromethylation of both enolizable and non-enolizable aldehydes and ketones by using difluoromethyl phenyl sulfone (1) as the fluoroalkylating agent. Although the chemical yields of the reactions are good to excellent, the observed diastereoselectivity is poor (dr = 1:1.04-2.03). The present synthetic methodology provides a convenient alternative for the preparation of alpha-(phenylsulfinyl)difluoromethylated carbinols that were previously synthesized via a two-step procedure. (C) 2007 Elsevier B.V. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000250619900025
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/24029
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Zhu LG,Li Y,Ni CF,et al. Nucleophilic (phenylsulfinyl)difluoromethylation of carbonyl compounds with difluoromethyl phenyl sulfoxide[J]. J. Fluor. Chem.,2007,128(10):1241-1247.
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