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学科主题: 氟化学
题名: Radical (phenylsulfonyl)difluoromethylation with iododifluoromethyl phenyl sulfone
其他题名: 利用一碘二氟甲基苯基砜进行自由基苯磺酰二氟甲基化反应
作者: Li Y(李亚) ; Liu J(刘俊) ; Zhang LJ(张来俊) ; Zhu LG(朱林桂) ; Hu JB(胡金波)
通讯作者: 胡金波
刊名: J. Org. Chem.
发表日期: 2007
卷: 72, 期:15, 页:5824-5827
收录类别: SCI
部门归属: 中科院上海有机所
英文摘要: An unprecedented radical (phenylsulfonyl)difluoromethylation of terminal alkenes with PhSO2CF2I has been achieved by using Et3B/air as an initiator. This synthetic methodology was also used in the one-pot regioselective preparation of PhSO2CF2-substituted alkanes, and in the regio- and stereoselective preparation of PhSO2CF2-substituted alkenes with high E/Z ratio (up to >= 100:1).
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000247992800046
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/24017
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Li Y,Liu J,Zhang LJ,et al. Radical (phenylsulfonyl)difluoromethylation with iododifluoromethyl phenyl sulfone[J]. J. Org. Chem.,2007,72(15):5824-5827.
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