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学科主题: 氟化学
题名: Selective fluoroalkylations with fluorinated sulfones, sulfoxides, and Sulfides
其他题名: 利用含氟砜、亚砜、硫醚类物质进行选择性氟烷基化
作者: Prakash, G. K. Surya ; Hu JB(胡金波)
通讯作者: Prakash, G. K. Surya
刊名: Accounts Chem. Res.
发表日期: 2007
卷: 40, 期:10, 页:921-930
收录类别: SCI
部门归属: 南加州大学; 中科院上海有机所
英文摘要: Efficient fluoroalkylations have been proven to be a highly useful strategy for the synthesis of bioactive fluorine-containing compounds and other materials. The design and use of a single category of reagents for multiple synthetic goals are much more attractive to preparative organic chemists. In this Account, we show how we have succeeded in the nucleophilic trifluoromethylation, difluoromethylation, difluoromethylenation, (phenylsulfonyl)difluoromethylation, (phenylthio)difluoromethylation, and monofluoromethylation as well as radical (phenylsulfonyl)difluoromethylation and electrophilic difluoromethylation by using fluorinated sulfones, sulfoxides, sulfides, or fluorinated sulfonium salts. The chemistry not only provides practically powerful synthetic methods, but the molecular design concept that we have developed may also be adopted to tackle other related chemical problems.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000250260800001
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/24013
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Prakash, G. K. Surya,Hu JB. Selective fluoroalkylations with fluorinated sulfones, sulfoxides, and Sulfides[J]. Accounts Chem. Res.,2007,40(10):921-930.
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