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学科主题: 氟化学
题名: Stereoselective nucleophilic monofluoromethylation of N-(tert-butanesulfinyl)imines with fluoromethyl phenyl sulfone
其他题名: 利用一氟甲基苯基砜对N-(叔丁基亚磺酰)亚胺的立体选择性一氟甲基化反应研究
作者: Li Y(李亚) ; Ni CF(倪传法) ; Liu J(刘俊) ; Zhang LJ(张来俊) ; Zheng J(郑吉) ; Zhu LG(朱林桂) ; Hu JB(胡金波)
通讯作者: 胡金波
刊名: Org. Lett.
发表日期: 2006
卷: 8, 期:8, 页:1693-1696
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所
英文摘要: Highly stereoselective nucleophilic monofluoromethylation of (R)-(tert-butanesulfinyl)imines with fluoromethyl phenyl sulfone was achieved to afford alpha-monofluoromethylamines with a nonchelation-controlled stereoselectivity mode. By using the same chemistry, (R)-(tert-butanesulfinyl)imines bearing a terminal tosylate (M) group can be converted to alpha-monofluoromethylated cyclic secondary amines with high stereoselectivity.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000236950400046
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/24009
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Li Y,Ni CF,Liu J,et al. Stereoselective nucleophilic monofluoromethylation of N-(tert-butanesulfinyl)imines with fluoromethyl phenyl sulfone[J]. Org. Lett.,2006,8(8):1693-1696.
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