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学科主题: 氟化学
题名: Convenient synthesis of difluoromethyl alcohols from both enolizable and non-enolizable carbonyl compounds with difluoromethyl phenyl sulfone difluoromethylation; fluorine; reductive desulfonylation
其他题名: 利用二氟甲基苯基砜和易烯醇化的及非烯醇化的羰基化合物来合成二氟甲基化的醇类化合物
作者: Prakash, GKS ; Hu JB(胡金波) ; WANG YING ; Olah, GA
通讯作者: Prakash, GKS
刊名: Eur. J. Org. Chem.
发表日期: 2005-01-01
期: 11, 页:2218-2223
收录类别: SCI
部门归属: 上海有机化学研究所; 南加州大学
英文摘要: A general and efficient nucleophilic difluoromethylation of carbonyl compounds (both enolizable and non-enolizable aldehydes and ketones) has been achieved by using a nucleophilic (phenylsulfonyl)difluoromethylation-reductive desul-fonylation strategy. Difluoromethyl phenyl sulfone acts as a difluoromethyl anion ("CF2H-") equivalent. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005).
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/23999
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Prakash, GKS,Hu JB,WANG YING,et al. Convenient synthesis of difluoromethyl alcohols from both enolizable and non-enolizable carbonyl compounds with difluoromethyl phenyl sulfone difluoromethylation; fluorine; reductive desulfonylation[J]. Eur. J. Org. Chem.,2005(11):2218-2223.
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