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学科主题: 天然产物有机化学
题名: Total syntheses of (S(p))-(+)- and (R(p))-(-)-spiniferin-1, a pair of unusual natural products with planar chirality
其他题名: (Sp)-(+)-和(Rp)-(-)-spiniferin-1, 一对平面光学天然产物的全合成
作者: Sun YS(孙云山) ; Ding K(丁凯) ; Tian WS(田伟生)
通讯作者: 田伟生
刊名: Chem. Commun.
发表日期: 2011-01-01
卷: 47, 期:37, 页:10437-10439
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: (S(p))-(+)-Spiniferin-1 and (R(p))-(-)-spiniferin-1, a pair of unusual marine natural products with planar chirality, were firstly synthesized via a polyfluoroalkanosulfonyl fluoride induced homoallylic carbocation rearrangement reaction. The chiral resolution and palladium-catalyzed beta-H elimination of allylic alcohol derivatives were considered as the key steps of these divergent syntheses.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/23890
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Recommended Citation:
Sun YS,Ding K,Tian WS. Total syntheses of (S(p))-(+)- and (R(p))-(-)-spiniferin-1, a pair of unusual natural products with planar chirality[J]. Chem. Commun.,2011,47(37):10437-10439.
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