中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 中科院天然产物有机化学重点实验室  > 期刊论文
学科主题: 天然产物有机化学
题名: 利用甾体皂甙元氧化降解工业废弃物(R)-4-甲基-δ-戊内酯合成松叶蜂性信息素(2S,3S,7S)-3,7-二甲基-2-十五醇乙酸酯和丙酸酯
其他题名: Practical synthesis of the main sex pheromones of pine sawflies (2S,3S,7S)-3,7-dimethylpentadecan-2-ol esters by utilizing (R)-4-methyl-delta-valerolactone obtained from the industrial waste
作者: 王子坤 ; 田伟生 ; 潘鑫复
通讯作者: 田伟生
刊名: 化学学报
发表日期: 2007-01-01
卷: 65, 期:8, 页:705-710
收录类别: SCI
部门归属: 兰州大学; 上海有机化学研究所
英文摘要: The synthesis of the sex pheromones of pine sawflies (2S,3S,7S)-3,7-dimethylpentadecan-2-yl acetate (2) and its propionate (3) by utilizing the industrial waste, (R)-4-methyl-6-valerolactone in the degradation of steroidal sapogenin was first reported in this paper. (R)-4-Methyl-b.-Valerolactone was transformed into (R)-methyl 5-bromo-4-methylpentanoate (5) which is a stable and easily reserved reagent. 5 then underwent a series of reaction involving coupling, reduction, bromination and addition to epoxide to give target molecules 2 and 3. This research result not only provides a concise synthetic method for (2S,3S,7S)-3,7-dimethylpentadecan-2-yI acetate (2) and propionate (3), but also enrichs the connotation of resource chemistry (the organic synthetic chemistry based on the rational utilization of resource compounds). Keywords
语种: 中文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/23866
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2007200.pdf(301KB)----开放获取--View Download

Recommended Citation:
王子坤,田伟生,潘鑫复. 利用甾体皂甙元氧化降解工业废弃物(R)-4-甲基-δ-戊内酯合成松叶蜂性信息素(2S,3S,7S)-3,7-二甲基-2-十五醇乙酸酯和丙酸酯[J]. 化学学报,2007,65(8):705-710.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[王子坤]'s Articles
[田伟生]'s Articles
[潘鑫复]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[王子坤]‘s Articles
[田伟生]‘s Articles
[潘鑫复]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2007200.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace