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学科主题: 天然产物有机化学
题名: Stereoselective synthesis of (2S,3S,7S)-3,7-dimethylpentadec-2-yI acetate and propionate, the sex pheromones of pine sawflies
其他题名: 松叶蜂信息素(2S,3S,7S)-3,7-二甲基十五醇乙酸酯和丙酸酯的合
作者: Wang ZK(王子坤) ; Xu QH(许启海) ; Tian WS(田伟生) ; Pan XF(潘鑫复)
通讯作者: 田伟生 ; 潘鑫复
刊名: Tetrahedron Lett.
发表日期: 2007-01-01
卷: 48, 期:42, 页:7549-7551
收录类别: SCI
部门归属: 兰州大学; 上海有机化学研究所
英文摘要: The stereoselective synthesis of (2S,3S,7S)-3,7-dimethylpentadec-2-yl acetate (2) and propionate (3) was accomplished by utilizing the cheap and easily available chiron (R)-4-methyl-delta-valerolactone (4). The key steps were chelation-controlled addition of Gilmann reagent to chiral beta-alkoxy aldehyde 12 and the Cu(I)-catalyzed coupling of Grignard reagent with bromoester 5 in the presence of NMP. (C) 2007 Published by Elsevier Ltd.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/23854
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Wang ZK,Xu QH,Tian WS,et al. Stereoselective synthesis of (2S,3S,7S)-3,7-dimethylpentadec-2-yI acetate and propionate, the sex pheromones of pine sawflies[J]. Tetrahedron Lett.,2007,48(42):7549-7551.
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