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Natural products synthesis by retro-Diels-Alder reaction
Alternative Title用反Diels-alder反应合成天然产物
Liu ZY(刘志煜); Chu XJ(褚新阶); He L(何菱); Xie YN(谢益农); Zhao LY(赵联运)
1997
Source Publication有机化学
ISSN0253-2786
Volume17Pages:0062-0065
Other Abstract天然产物全合成主要在于发展有效的方法以组成碳骨架和立体控制引 入必须的官能团。本文利用刚性分子三环癸二烯酮(1)为原料, 立体 控制地引入取代基及官能团组成目标分子所需的碳骨架及官能团后进 行反Diels-Alder反应释放出取代环戊烯酮, 从而进一步合成目标分 子克罗莫酸C-12-D-13, F4, B7, 蚊皇识别信息素18,6-表蚊皇识别信 息素19以及经30获得的32, 后者是全合成大环内酯生物碱27的关键中 间体。用酶催化反应不对称乙酰化内消旋二醇24c得光学活性单乙酯 24d(81%产率, 98.3%对映体过量值)。24d经过官能团转换可得(+)及 (-)1, 从(-)1用相似的反应合成了光学活性蚁皇识别信息素
Subject Area天然产物有机化学
Department科学院上海有机化学研究所
Language英语
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/23582
Collection中科院天然产物有机化学重点实验室
Corresponding AuthorLiu ZY(刘志煜)
Recommended Citation
GB/T 7714
Liu ZY,Chu XJ,He L,et al. Natural products synthesis by retro-Diels-Alder reaction[J]. 有机化学,1997,17:0062-0065.
APA 刘志煜,褚新阶,何菱,谢益农,&赵联运.(1997).Natural products synthesis by retro-Diels-Alder reaction.有机化学,17,0062-0065.
MLA 刘志煜,et al."Natural products synthesis by retro-Diels-Alder reaction".有机化学 17(1997):0062-0065.
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