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学科主题: 有机化学
题名: Modular synthesis of chiral homo- and heterotrisoxazolines. Improving the enantioselectivity in the asymmetric Michael addition of indole to benzylidene malonate
其他题名: 模块法合成同手性和杂手性三恶唑啉。提高吲哚和亚苯基丙二酸的不对称Michael加成的对映选择性。
作者: Ye MC(叶萌春) ; Li B(李斌) ; Zhou J(周剑) ; Sun XL(孙秀丽) ; Tang Y(唐勇)
通讯作者: 唐勇
刊名: J. Org. Chem.
发表日期: 2005
卷: 70, 期:15, 页:6108-6110
收录类别: SCI
部门归属: 上海有机化学研究所金属有机化学国家重点实验室
英文摘要: A simple approach to a diverse set of chiral trisoxazolines is described. Deprotonation of bisoxazolines 2, followed by treatment of 2-chloromethyloxazolines 3, affords chiral trisoxazolines, including chiral homo- and hetero-trisoxazolines in good to high yields. These trisoxazolines are successfully applied in the asymmetric reaction of indole with benzylidene malonate, and ee's up to 93% were obtained.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000230629700044
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/23394
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Ye MC,Li B,Zhou J,et al. Modular synthesis of chiral homo- and heterotrisoxazolines. Improving the enantioselectivity in the asymmetric Michael addition of indole to benzylidene malonate[J]. J. Org. Chem.,2005,70(15):6108-6110.
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