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学科主题: 氟化学
题名: 1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU) Catalyzed Regiospecific and Diastereoselective Reaction of Chiral N-(tert-Butanesulfinyl)ketimines and alpha,beta-Unsaturated Trifluoromethyl Ketones
其他题名: DBU 催化的手性N-叔丁基酮亚胺与三氟甲基α,β-不饱和酮的区域和立体选择性加成反应
作者: Zhang F(张帆) ; Liu ZJ(刘振江) ; Liu JT(刘金涛)
通讯作者: 刘金涛
刊名: Chin. J. Chem.
发表日期: 2011
卷: 29, 期:12, 页:2727-2731
收录类别: SCI
部门归属: 中科院上海有机化学研究所; 上海应用技术学院
英文摘要: The reaction of chiral N-(tert-butanesulfinyl)ketimines and alpha,beta-unsaturated trifluoromethyl ketones catalyzed by DBU was achieved under mild conditions. 1,2-Addition products, precursors of chiral trifluoromethylated 1,3-amino alcohols, were obtained diastereoselectively (dr value up to 95 : 5) in moderate yields (up to 76%). A possible catalytic cycle was proposed.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000298016700028
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/23392
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Zhang F,Liu ZJ,Liu JT. 1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU) Catalyzed Regiospecific and Diastereoselective Reaction of Chiral N-(tert-Butanesulfinyl)ketimines and alpha,beta-Unsaturated Trifluoromethyl Ketones[J]. Chin. J. Chem.,2011,29(12):2727-2731.
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