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学科主题: 氟化学
题名: Asymmetric aza-Henry reaction of chiral fluoroalkyl alpha,beta-unsaturated N-tert-butanesulfinyl ketoimines: an efficient approach to enantiopure fluoroalkylated alpha,beta-diamines and alpha,beta-diamino acids
其他题名: 手性氟烷基-α,β-不饱和酮-N-叔丁基亚磺酰亚胺的不对称aza-Henry反应
作者: Zhang F(张帆) ; Liu ZJ(刘振江) ; Liu JT(刘金涛)
通讯作者: 刘金涛
刊名: Org. Biomol. Chem.
发表日期: 2011
卷: 9, 期:10, 页:3625-3628
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: The aza-Henry reaction of chiral fluoroalkyl alpha,beta-unsaturated N-tert-butanesulfinyl ketoimines and nitromethane was achieved in the presence of 0.2 equivalent of anhydrous potassium carbonate to give the corresponding adducts diastereoselectively in high yields. Transformations which highlighted the synthetic potential of these aza-Henry adducts were also performed.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000289897200007
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/23388
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Zhang F,Liu ZJ,Liu JT. Asymmetric aza-Henry reaction of chiral fluoroalkyl alpha,beta-unsaturated N-tert-butanesulfinyl ketoimines: an efficient approach to enantiopure fluoroalkylated alpha,beta-diamines and alpha,beta-diamino acids[J]. Org. Biomol. Chem.,2011,9(10):3625-3628.
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