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学科主题: 氟化学
题名: Synthesis and selective carbocupration reaction of fluorine-containing enynic esters, enynylphosphine oxides, and enynyl phosphates
其他题名: Synthesis and selective carbocupration reaction of fluorine-containing enynic esters, enynylphosphine oxides, and enynyl phosphates
作者: Mei YQ(梅英桥) ; Liu JT(刘金涛)
通讯作者: 刘金涛
刊名: Tetrahedron
发表日期: 2008-01-01
卷: 64, 期:37, 页:8801-8806
收录类别: SCI
部门归属: 上海有机所
英文摘要: Some new fluorine-containing enynic esters, enynylphosphine oxides, and enynylphosphates were synthesized stereoselectively in good yields by the dehydrohalogenation reaction of fluoroalkylated 3-iodoacrylates, 2-iodovinylphosphonates, and 2-iodovinylphosphine oxides under basic conditions. These fluorine-containing enynic compounds could undergo carbocupration reaction with organocopper reagents and the vinylcopper intermediates formed in situ could further react with some electrophiles such as allyl bromide, phenylselenyl bromide, and iodine to give the corresponding polysubstituted fluorine-containing dienoic esters, phosphates, and phosphine oxides with high regio- and stereoselectivity. (C) 2008 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000258841100030
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/23362
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Mei YQ,Liu JT. Synthesis and selective carbocupration reaction of fluorine-containing enynic esters, enynylphosphine oxides, and enynyl phosphates[J]. Tetrahedron,2008,64(37):8801-8806.
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