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学科主题: 氟化学
题名: A practical diastereoselective synthesis of beta-hydroxy-beta-trifluoromethyl imines
其他题名: A practical diastereoselective synthesis of beta-hydroxy-beta-trifluoromethyl imines
作者: Liu ZJ(刘振江) ; Mei YQ(梅英桥) ; Liu JT(刘金涛)
通讯作者: 刘金涛
刊名: Tetrahedron
发表日期: 2007
卷: 63, 期:4, 页:855-860
收录类别: SCI
部门归属: 上海有机所
英文摘要: The asymmetric carbon-carbon bond formation reaction affording chiral (3-hydroxy-(3-trifluoromethyl imines is reported involving the nucleophilic addition of sulfinimine anions derived froth chiral N-(tert-butanesulfinyl) ketimines to trifluoromethyl ketones. The reaction tolerates a wide range of nucleophiles, giving the condensation products in good to excellent total yields with good diastereoselectivities (up to 85:15 dr). (c) 2006 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000244196200004
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/23352
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Liu ZJ,Mei YQ,Liu JT. A practical diastereoselective synthesis of beta-hydroxy-beta-trifluoromethyl imines[J]. Tetrahedron,2007,63(4):855-860.
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