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学科主题: 氟化学
题名: Regio- and stereoselective addition of perfluoroalkyl iodides to allenes conjugated with carbon-oxygen or phosphorus-oxygen double bonds
其他题名: Regio- and stereoselective addition of perfluoroalkyl iodides to allenes conjugated with carbon-oxygen or phosphorus-oxygen double bonds
作者: Mei YQ(梅英桥) ; Liu JT(刘金涛) ; Liu ZJ(刘振江)
通讯作者: 刘金涛
刊名: Synthesis
发表日期: 2007
期: 5, 页:739-743
收录类别: SCI
部门归属: 上海有机所
英文摘要: In the presence of sodium dithionite, allenes conjugated with a carbon-oxygen or a phosphorus-oxygen double bond, such as allenic phosphonates, phosphine oxides and allenecarboxylates, reacted readily with perfluoroalkyl iodides at room temperature to give the corresponding addition products in moderate yields with complete regioselectivity and stereoselectivity. Perfluoroalkyl groups were introduced into the terminal position of allenes and addition products with the E-configuration were obtained selectively by the reaction.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000245009500016
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/23348
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Mei YQ,Liu JT,Liu ZJ. Regio- and stereoselective addition of perfluoroalkyl iodides to allenes conjugated with carbon-oxygen or phosphorus-oxygen double bonds[J]. Synthesis,2007(5):739-743.
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