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学科主题: 氟化学
题名: Conjugate additions of secondary amines and water to allenyl perfluoroalkyl sulfones water
其他题名: 二级胺和水对全氟烷基联烯砜的共轭加成
作者: Wang XJ(王小进) ; Lin Y(林云) ; Liu JT(刘金涛)
通讯作者: 刘金涛
刊名: Chin. J. Chem.
发表日期: 2006-01-01
卷: 24, 期:6, 页:775-780
收录类别: SCI
部门归属: 上海有机所
英文摘要: Preparation of allenyl perfluoroalkyl sulfones from perfluoroalkyl sulfinyl chlorides and their reactions with secondary amines and water were studied. At room temperature secondary amines reacted readily with allenyl perfluoroalkyl sulfones to give the corresponding enamine adducts, which underwent rearrangement to afford conjugate enamines in refluxing toluene. Good diastereoslectivities were observed in the addition of diethylamine to gamma-ethyl-gamma-methylallenyl perfluoroalkyl sulfones. In refluxing acetonitrile, water could also undergo the similar addition with allenyl perfluoroalkyl sulfones.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/23338
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Wang XJ,Lin Y,Liu JT. Conjugate additions of secondary amines and water to allenyl perfluoroalkyl sulfones water[J]. Chin. J. Chem.,2006,24(6):775-780.
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