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学科主题: 氟化学
题名: Organosulfur- or organoselenium-induced intramolecular cycloaddition of beta-allenic alpha-difluoromethylenephosphonic acid monoesters: Synthesis of novel cyclic phosphate mimics phosphate mimic; alpha-difluoromethylenephostone; organoselenium; organosulfur; cyclization
其他题名: 有机硫或有机硒诱导的α-二氟亚甲基-β-联烯膦酸单酯的分子内环化反应: 环磷酸酯模拟物的合成
作者: Lin Y(林云) ; Liu JT(刘金涛)
通讯作者: 刘金涛
刊名: Synlett
发表日期: 2006-01-01T00:00:00Z
期: 14, 页:2227-2230
收录类别: SCI
部门归属: 中科院上海有机所
英文摘要: Novel cyclic phosphate mimics, gamma-organosulfur or organoselenium substituted alpha-difluoromethylenephostones were synthesized in good yields with high regioselectivity under mild conditions by the electrophilic cyclization of beta-allenic alpha-difluoromethylenephosphonic acid monoesters induced by ArSCl or ArSeCl. The reaction represents the first example of an intramolecular addition of phosphonic acid monoesters to beta-allenic carbon-carbon double bonds.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/23334
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Lin Y,Liu JT. Organosulfur- or organoselenium-induced intramolecular cycloaddition of beta-allenic alpha-difluoromethylenephosphonic acid monoesters: Synthesis of novel cyclic phosphate mimics phosphate mimic; alpha-difluoromethylenephostone; organoselenium; organosulfur; cyclization[J]. Synlett,2006(14):2227-2230.
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