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学科主题: 氟化学
题名: Unexpected formation of polysubstituted 1-azabutadienes and 1,3-dioxanes from the reaction of 3-fluoroalkyl-3-arylaminoacrylic acid esters with formaldehyde
其他题名: 3-氟烷基-3-芳胺基丙烯酸酯与甲醛反应意外地生成多取代1-氮杂丁二烯和1,3-二氧六环
作者: Zhao FL(赵富录) ; Liu JT(刘金涛)
通讯作者: 刘金涛
刊名: J. Org. Chem.
发表日期: 2005
卷: 70, 期:10, 页:3801-3805
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: The reaction of 3-fluoroalkyl-3-arylaminoacrylic acid esters with formaldehyde was described. In the presence of a catalytic amount of triethylamine, the reaction took place readily in acetonitrile at 70 ° C to give the corresponding 2-fluoroalkyl-1-azabutadienes in good yields. cis-Fluoroalkylated 1,3-dioxanes were obtained predominantly when the aryl ring contained an electron-withdrawing group and the reaction was carried out at room temperature under catalysis of triethylamine and tetrabutylammonium bromide. A possible mechanism was proposed.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000228983300004
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/23328
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Zhao FL,Liu JT. Unexpected formation of polysubstituted 1-azabutadienes and 1,3-dioxanes from the reaction of 3-fluoroalkyl-3-arylaminoacrylic acid esters with formaldehyde[J]. J. Org. Chem.,2005,70(10):3801-3805.
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