SIOC OpenIR  > 中科院有机氟化学重点实验室
Unexpected formation of polysubstituted 1-azabutadienes and 1,3-dioxanes from the reaction of 3-fluoroalkyl-3-arylaminoacrylic acid esters with formaldehyde
其他题名3-氟烷基-3-芳胺基丙烯酸酯与甲醛反应意外地生成多取代1-氮杂丁二烯和1,3-二氧六环
Zhao FL(赵富录); Liu JT(刘金涛)
2005
发表期刊J. Org. Chem.
ISSN0022-3263
卷号70期号:10页码:3801-3805
摘要The reaction of 3-fluoroalkyl-3-arylaminoacrylic acid esters with formaldehyde was described. In the presence of a catalytic amount of triethylamine, the reaction took place readily in acetonitrile at 70 ° C to give the corresponding 2-fluoroalkyl-1-azabutadienes in good yields. cis-Fluoroalkylated 1,3-dioxanes were obtained predominantly when the aryl ring contained an electron-withdrawing group and the reaction was carried out at room temperature under catalysis of triethylamine and tetrabutylammonium bromide. A possible mechanism was proposed.
学科领域氟化学
部门归属中科院上海有机化学研究所
URL查看原文
收录类别SCI
语种英语
WOS记录号WOS:000228983300004
引用统计
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/23328
专题中科院有机氟化学重点实验室
通讯作者Liu JT(刘金涛)
推荐引用方式
GB/T 7714
Zhao FL,Liu JT. Unexpected formation of polysubstituted 1-azabutadienes and 1,3-dioxanes from the reaction of 3-fluoroalkyl-3-arylaminoacrylic acid esters with formaldehyde[J]. J. Org. Chem.,2005,70(10):3801-3805.
APA 赵富录,&刘金涛.(2005).Unexpected formation of polysubstituted 1-azabutadienes and 1,3-dioxanes from the reaction of 3-fluoroalkyl-3-arylaminoacrylic acid esters with formaldehyde.J. Org. Chem.,70(10),3801-3805.
MLA 赵富录,et al."Unexpected formation of polysubstituted 1-azabutadienes and 1,3-dioxanes from the reaction of 3-fluoroalkyl-3-arylaminoacrylic acid esters with formaldehyde".J. Org. Chem. 70.10(2005):3801-3805.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
2005205.pdf(148KB) 开放获取--请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[赵富录]的文章
[刘金涛]的文章
百度学术
百度学术中相似的文章
[赵富录]的文章
[刘金涛]的文章
必应学术
必应学术中相似的文章
[赵富录]的文章
[刘金涛]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。