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学科主题: 氟化学
题名: Reactions of 2,2-dihydropolyfluoroalkylaldehydes with amines: a facile synthetic method for fluoroalkyl enaminoketones
其他题名: 2,2-二氢多氟烷基醛与胺的反应: 一种合成氟烷基烯胺铜的简便方法
作者: Yang XJ(杨先金) ; Liu JT(刘金涛) ; Zhao FL(赵富录)
通讯作者: 刘金涛
刊名: J. Fluor. Chem.
发表日期: 2004
卷: 125, 期:3, 页:415-419
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所有机氟实验室
英文摘要: Reactions of 2,2-dihydropolyfluoroalkylaldehydes (1) with amines (2) were studied. Both aliphatic amines and electron-deficient aromatic amines readily reacted with I in acetonitrile and water under reflux to give fluoroalkyl enaminoketones (3) in high yields, while no condensed products were obtained by reactions of 1 with electron-rich aromatic amines under similar conditions. In the presence of triethylamine, however, the reaction of 1 with electron-rich aromatic amines at room temperature gave 3 in low yields. (C) 2003 Elsevier B.V. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000220050100008
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/23320
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Yang XJ,Liu JT,Zhao FL. Reactions of 2,2-dihydropolyfluoroalkylaldehydes with amines: a facile synthetic method for fluoroalkyl enaminoketones[J]. J. Fluor. Chem.,2004,125(3):415-419.
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