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学科主题: 金属有机化学
题名: Facile streoselective synthesis of aryl substituted α,β-Unsaturated esters containing a trifluoromethyl group
其他题名: Facile streoselective synthesis of aryl substituted α,β-Unsaturated esters containing a trifluoromethyl group
作者: Pan RQ(潘瑞琪) ; Wang PA(王平安) ; Deng MZ(邓敏智)
通讯作者: 邓敏智
刊名: Heteroatom Chem.
发表日期: 2002-01-01
卷: 13, 期:3, 页:287-290
收录类别: SCI
部门归属: Department of Chemistry, Northwest University; 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: The suzuki-type cross-coupling reaction of arylboronic acids 3 with ethyl (Z)-3-iodo-4,4,4-trifluoro-2-butenoate 2, which was generated by hydroiodination of available ethyl 4,4,4-trifluoro-2-butynoate 1, to afford ethyl (E)-3-aryl-4,4,4-trifluoro2-butenoates 4, was studied for the first time, It was found that under the optimum conditions the crosscoupling reaction could readily give 4 as the sole E-isomer in 76-91% yields.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/23108
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Pan RQ,Wang PA,Deng MZ. Facile streoselective synthesis of aryl substituted α,β-Unsaturated esters containing a trifluoromethyl group[J]. Heteroatom Chem.,2002,13(3):287-290.
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