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学科主题: 金属有机化学
题名: Selective reduction of stereodefined cyclopropyl substituted scrylate esters to the corresponding propionate esters
其他题名: 选择性还原立体专一的环丙基取代的丙烯酸酯到相应的丙酸酯
作者: He R(贺溶) ; Deng MZ(邓敏智)
通讯作者: 邓敏智
刊名: Tetrahedron
发表日期: 2002-01-01
卷: 58, 期:38, 页:7613-7617
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: Stereodefined cyclopropyl substituted acrylate esters were selectively reduced to the corresponding propionate esters by sodium borohydride in methanol/DMF with a catalytic amount of CoCl^2 without the opening of the cycloproane ring. The configuration and chirality of the stereodefined cyclopropyl function were retained in the reaction. Combined with the cross-coupling reaction of stereodefined cyclopropylboronic acids with bromoacrylate esters or alkenyl triflates, the reaction method provides a novel route to stereodefined 3-cyclopropyl propionate ester, an important subunit existing in a wide range of natural compounds.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/23102
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
He R,Deng MZ. Selective reduction of stereodefined cyclopropyl substituted scrylate esters to the corresponding propionate esters[J]. Tetrahedron,2002,58(38):7613-7617.
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