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学科主题: 有机化学
题名: A novel method for the construction of (Z,E)-or (Z,Z)-conjugated alkakienyl carboxylates
其他题名: 一个构建立体专用的(Z,E), (Z,E)共轭双烯羟酸酯的新方法
作者: He R(贺溶) ; Deng MZ(邓敏智)
通讯作者: 邓敏智
刊名: Org. Lett.
发表日期: 2002-01-01
卷: 4, 期:16, 页:2759-2762
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: The stereocontrolled dehydrobromination of 1,2-dibromoethyl carboxylates giving (Z)-2-bromovinyl carboxylates could readily be approached by using DBU and a catalytic amount of hydroquinone as a base at-78℃. The first investigation of the Suzuki-type cross-coupling of (Z)-2-bromovinyl carboxylates as electrophiles with stereodefined alkenylboronic acids provides a novel method for the construction of (Z,E)-or (Z,Z)-conjugated alkadienyl carboxylate moieties, which are often present in a range of natural products.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/23098
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
He R,Deng MZ. A novel method for the construction of (Z,E)-or (Z,Z)-conjugated alkakienyl carboxylates[J]. Org. Lett.,2002,4(16):2759-2762.
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