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学科主题: 有机化学
题名: Cross-coupling reaction of cy-clopropylboronic acids with aryl omega-halo-oxo-perfluoroalkyl-sulfonates
其他题名: Cross-coupling reaction of cy-clopropylboronic acids with aryl omega-halo-oxo-perfluoroalkyl-sulfonates
作者: Yao ML(姚敏良) ; Wang JP(王家坡) ; Deng MZ(邓敏智)
刊名: Chin. Sci. Bull.
发表日期: 2001
卷: 46, 期:15, 页:1277-1281
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所
英文摘要: The cross-coupling reaction of cyclopropylboronic acids with aryl omega -halo-oxo-perfluoroalkylsulfonates is investigated. It was found that the stereodefined cyclopropylboronic acids can readily react with aryl omega -halo-oxo-perfluoroalkylsulfonates to give the corresponding cross-coupling products in high yields under the appropriate conditions and in the presence of transition metal catalysts. For the reaction of various aryl perfluoroalkylsulfonates bearing the substituents, the use of corresponding bases was essential. During these reactions, the cyclopropyl configurations of cyclopropylboronic acids are retained. Thus, the procedure provides a new convenient route to stereodefined cyclopropane derivatives from phenols and commerce-available omega -chloro-oxo-perfluoroalkylsulfonyl fluoride.
语种: 英语
WOS记录号: WOS:000171106200009
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/23096
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Yao ML,Wang JP,Deng MZ. Cross-coupling reaction of cy-clopropylboronic acids with aryl omega-halo-oxo-perfluoroalkyl-sulfonates[J]. Chin. Sci. Bull.,2001,46(15):1277-1281.
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