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学科主题: 金属有机化学
题名: A novel Suzuki-type cross-coupling reaction of cyclopropylboronic esters with benzyl bromides
其他题名: 一个新奇的环丙基硼酸酯与苄溴的Suzuki类型交叉偶亮反应
作者: Chen H(陈寒) ; Deng MZ(邓敏智)
通讯作者: 邓敏智
刊名: J. Chem. Soc.-Perkin Trans. 1
发表日期: 2000
期: 10, 页:1609-1613
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: The Suzuki-type coupling reaction of cyclopropylboronic acids (esters) with benzyl bromides readily takes place by using Ag^2O with KOH as the base. The reaction rate and the cross-coupling product yields of cyclopropylbbroMte esters of ethylene glycol or propane-1,3-diol were higher and better than those of cyclopropylfloronic acids. However, the cohpling reaction of the cyclopropylboronate esters of glycol with larger substituents was sluggish. The highly optically active benzyl-substituted cyclopropanes could be obtained by the coupling reactions of corrp.ppnding optically active cyclopropylboronate esters with benzyl bromides. A novel, ideal method fat preparing stereo-defined benzyl-substituted cyclopropanes, especially optically active benryl-substituted cyclopropanes, is described here.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000087318600019
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/23086
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Chen H,Deng MZ. A novel Suzuki-type cross-coupling reaction of cyclopropylboronic esters with benzyl bromides[J]. J. Chem. Soc.-Perkin Trans. 1,2000(10):1609-1613.
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