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学科主题: 有机化学
题名: Efficient and Regioselective 9-Endo Cyclization of alpha-Carbamoyl Radicals
其他题名: 高效及区域选择性的α-酰胺基自由基9-endo环合反应
作者: Song LY(宋立彦) ; Liu K(刘鲲) ; Li CZ(李超忠)
刊名: Org. Lett.
发表日期: 2011-01-01
卷: 13, 期:13, 页:3434-3437
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: With the promotion of Lewis acid BF(3)center dot OEt(2), various N-(hex-5-enyl)-2-iodoalkanamides underwent efficient and regioselective 9-endo iodine-atom-transfer radical cyclization reactions at room temperature. The cyclized products were readily converted to the corresponding azonan-2-ones by reduction with Bu(3)SnH or to hexahydroindolizin-3(5H)-ones by treatment with aqueous Na(2)CO(3) in a one-pot, two-stage manner.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000291920800038
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/22864
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Song LY,Liu K,Li CZ. Efficient and Regioselective 9-Endo Cyclization of alpha-Carbamoyl Radicals[J]. Org. Lett.,2011,13(13):3434-3437.
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