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Self-protection: The advantage of radical oligomeric mixtures in organic synthesis
Alternative Title自我保护: 自由基低聚混合物在有机合成中的优势
Yu H(于辉); Li CZ(李超忠)
2004
Source PublicationJ. Org. Chem.
ISSN0022-3263
Volume69Issue:1Pages:142-145
AbstractAtom-transfer radical oligomers of allyl iodoacetates were converted to 4-pentenoic acids upon treatment with zinc. Reactions of the radical oligomers of various omega-alkenyl iodoacetates with Grignard reagents afforded the corresponding substituted tetrahydrofuran derivatives. These results indicated that radical oligomeric mixtures not only serve as versatile intermediates in organic synthesis, but also exhibit unique advantages in that the oligomeric mixtures are self-protected and the deoligomerization functions as the simultaneous deprotection.
Subject Area有机化学
Department中国科学院上海有机化学研究所元素有机化学实验室
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Indexed BySCI
Language英语
WOS IDWOS:000187897800018
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/22798
Collection中科院天然产物有机化学重点实验室
Corresponding AuthorLi CZ(李超忠)
Recommended Citation
GB/T 7714
Yu H,Li CZ. Self-protection: The advantage of radical oligomeric mixtures in organic synthesis[J]. J. Org. Chem.,2004,69(1):142-145.
APA 于辉,&李超忠.(2004).Self-protection: The advantage of radical oligomeric mixtures in organic synthesis.J. Org. Chem.,69(1),142-145.
MLA 于辉,et al."Self-protection: The advantage of radical oligomeric mixtures in organic synthesis".J. Org. Chem. 69.1(2004):142-145.
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