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学科主题: 金属有机化学
题名: First alkyl radical additions to (η~6-arene)tricarbonylmanganese complexes
其他题名: 首例烷基自由基对芳基三羰基锰络合物的加成
作者: Lin HC(林和春) ; Zhang HJ(张宏军) ; Yang L(杨立) ; Li CZ(李超忠)
通讯作者: 李超忠
刊名: Org. Lett.
发表日期: 2002-01-01T00:00:00Z
卷: 4, 期:5, 页:823-825
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所;兰州大学应用有机国家重点实验室
英文摘要: Reaction of alkylmercury chlorides with arene manganess tricarbonyl complexes in the presence of Nal led to the formation of the additionreduction products. The mechanism was postulated to be the alkyl radical addition to ArMn(CO)^3+ cation to form the corresponding 17 valence electron intermediate, which was then reduced by alkylmercury chloride via a singlet electron transfer process to afford the product and regenerate an alkyl radical.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/22776
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Lin HC,Zhang HJ,Yang L,et al. First alkyl radical additions to (η~6-arene)tricarbonylmanganese complexes[J]. Org. Lett.,2002,4(5):823-825.
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