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学科主题: 生命有机化学
题名: Hihgly efficient synthesis of sterically hindered peptides containing N-methylated amino acid residues using a novel 1H-benzimidazolium salt
其他题名: 含N-甲基氨基酸的立体障碍肽的高效合成(用新型1H-Benzimidazolium salt)
作者: Li P(李鹏) ; Xu JC(徐杰诚)
通讯作者: 徐杰诚
刊名: Tetrahedron
发表日期: 2000-01-01
卷: 56, 期:51, 页:9949-9955
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所生命有机化学国家重点实验室
英文摘要: Novel 1H-benzimidazolium type petide coupling reagent, CMBI, w3as designed, synthesized, and shown to be efficient in the promotion of the formation of sterically hindered amide and ester bonds. Its high efficiency was proved by model reaction tests and the successful synthesis of various hindered oligopeptides and peptide segments containing N-methyl amino acid residues with fast reaction speeds, low racemization and excellent yields. A mechanism for amide bond formation mediated by the reagent was proposed.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/22636
Appears in Collections:上海有机化学研究所_期刊论文

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Recommended Citation:
Li P,Xu JC. Hihgly efficient synthesis of sterically hindered peptides containing N-methylated amino acid residues using a novel 1H-benzimidazolium salt[J]. Tetrahedron,2000,56(51):9949-9955.
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