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学科主题: 金属有机化学
题名: Chiral phosphoric acid-catalysed Friedel-Crafts alkylation reaction of indoles with racemic spiro indolin-3-ones
其他题名: 手性磷酸催化的吲哚与消旋螺环吲哚啉-3-酮的Friedel-Crafts烷基化反应
作者: Yin Q(殷勤) ; You SL(游书力)
通讯作者: 游书力
刊名: Chem. Sci.
发表日期: 2011
卷: 2, 期:7, 页:1344-1348
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: Chiral phosphoric acid-catalysed Friedel-Crafts alkylation reactions of indoles, pyrrole and 3-(dimethylamino) phenol with racemic spiro indolin-3-ones have been realised. With 5 mol% (S)-TRIP, Friedel-Crafts adducts bearing a quaternary stereocentre were obtained in up to 99% yield and 99% ee. The reaction features readily available, stable starting materials and delivers synthetically useful but challenging products.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000291610600019
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/22536
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Yin Q,You SL. Chiral phosphoric acid-catalysed Friedel-Crafts alkylation reaction of indoles with racemic spiro indolin-3-ones[J]. Chem. Sci.,2011,2(7):1344-1348.
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