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学科主题: 金属有机化学
题名: Stereoselective synthesis of gamma-butyrolactones via organocatalytic annulations of enals and keto esters
其他题名: Stereoselective synthesis of gamma-butyrolactones via organocatalytic annulations of enals and keto esters
作者: Li Y(李毅) ; Zhao ZA(赵卓安) ; He H(贺虎) ; You SL(游书力)
通讯作者: 游书力
刊名: Adv. Synth. Catal.
发表日期: 2008
卷: 350, 期:11-12, 页:1885-1890
收录类别: SCI
部门归属: 上海有机所
英文摘要: 4,5,5-Trisubstituted gamma-butyrolactones bearing two stereocenters including one quaternary carbon center have been synthesized in excellent yields via N-heterocyclic carbene-catalyzed annulations of enals and ketoesters. Chiral N-heterocyclic carbenes were used to tune the diastereoselectivity up to an 83/17 cis/trans ratio and the enantioselectivity up to 78% ee (trans isomer).
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000258503600031
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/22474
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Li Y,Zhao ZA,He H,et al. Stereoselective synthesis of gamma-butyrolactones via organocatalytic annulations of enals and keto esters[J]. Adv. Synth. Catal.,2008,350(11-12):1885-1890.
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