中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 金属有机化学国家重点实验室  > 期刊论文
学科主题: 金属有机化学
题名: Remarkable reactions of cationic carbyne complexes of manganese, rhenium, and diiron with carbonylmetal anions
其他题名: 锰,铼和双铁阳离子卡拜络合物与羰基金属阴离子的新奇反应
作者: Chen JB(陈家碧) ; Wang RT(王瑞涛)
通讯作者: 陈家碧
刊名: Coord. Chem. Rev.
发表日期: 2002
卷: 231, 期:1-2, 页:109-149
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: The cationic carbyne complexes of manganese and rhenium [η~5C^5H^5(CO)^2Mn≡CPh]BBr^4(1) and [η~5C^5H^5(CO)^2Re≡CPh]BBr^4(2), are the entry points for the synthesis of a variety of di-or tri-metal bridging carbene and bridging carbyne complexes resulting from nucleophilic attack on the carbyne carbon. Both cationic complexes, 1 and 2 undergo a wide range of reactions with carbonylmetal mono-and di-anions, mixed-dimeatal carbonyl anions, and reactive salts. Analogous studies of diiron cationic carbyne complexes [Fe^2(μ-CO)(μ-Car)(CO)^2(η~5-C^5H^5)^2]BBr^4 (Ar=C^6H^5, p-MeC^6H^4) and [Fe^2(μ-CO)(μ-Car)(CO)^2{η~5-C^5H^4)^2Si-Me^2}]BBr^4(Ar=C^6H^5,p-MeC^6H^4, p-CF^3C^6H^4) are also reviewed.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000178013500006
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/22296
Appears in Collections:金属有机化学国家重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2002095.pdf(2409KB)----开放获取--View Download

Recommended Citation:
Chen JB,Wang RT. Remarkable reactions of cationic carbyne complexes of manganese, rhenium, and diiron with carbonylmetal anions[J]. Coord. Chem. Rev.,2002,231(1-2):109-149.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[陈家碧]'s Articles
[王瑞涛]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[陈家碧]‘s Articles
[王瑞涛]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2002095.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace