中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 金属有机化学国家重点实验室  > 期刊论文
学科主题: 金属有机化学
题名: Half-Sandwich Indenyl Rare Earth Metal Dialkyl Complexes: Syntheses, Structures, and Catalytic Activities of (1,3-(SiMe3)(2)C9H5)Ln(CH2SiMe3)(2)(THF)
其他题名: 单茚基稀土金属双烷基化合物: (1,3-(SiMe3)2C9H5)Ln(CH2SiMe3)2(THF)的合成, 结构及催化活性
作者: Xu X(徐信) ; Chen YF(陈耀峰) ; Feng J(冯健) ; Zou G(邹刚) ; Sun J(孙杰)
通讯作者: 陈耀峰
刊名: Organometallics
发表日期: 2010
卷: 29, 期:3, 页:549-553
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所; 华东理工大学
英文摘要: Reactions of 1,3-bis(trimethylsilyl)indene with Ln(CH2SiMe3)(3)(THF)(2) gave half-sandwich rare earth metal complexes (1,3-(SiMe3)(2)C9H5)Ln(CH2SiMe3)(2)(THF) (Ln = Y, Lu, Dy). These complexes were characterized by single-crystal X-ray diffraction, which showed the eta(5) hapticity of indenyl ligands in all of the complexes. The catalytic behaviors of the complexes for intramolecular hydroamination of aminoalkenes were investigated. The catalytic activity increased with increasing the metal ion size. and the Y and Dy complexes showed excellent activities to a variety aminoalkenes.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000274015800009
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/21433
Appears in Collections:金属有机化学国家重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2010484.pdf(782KB)----开放获取--View Download

Recommended Citation:
Xu X,Chen YF,Feng J,et al. Half-Sandwich Indenyl Rare Earth Metal Dialkyl Complexes: Syntheses, Structures, and Catalytic Activities of (1,3-(SiMe3)(2)C9H5)Ln(CH2SiMe3)(2)(THF)[J]. Organometallics,2010,29(3):549-553.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[徐信]'s Articles
[陈耀峰]'s Articles
[冯健]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[徐信]‘s Articles
[陈耀峰]‘s Articles
[冯健]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2010484.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace