中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 金属有机化学国家重点实验室  > 期刊论文
学科主题: 金属有机化学
题名: Novel thermolytic products and their structures derived from thermolysis of isomerized products of spiro[4.4]nona-1,3-diene(dicarbonyl)[ethoxy(aryl) carbene]iron phosphine adducts [(eta(3)-C9H12)Fe{C(OC2H5)Ar}(CO)(2)PPh3]
其他题名: Novel thermolytic products and their structures derived from thermolysis of isomerized products of spiro[4.4]nona-1,3-diene(dicarbonyl)[ethoxy(aryl) carbene]iron phosphine adducts [(eta(3)-C9H12)Fe{C(OC2H5)Ar}(CO)(2)PPh3]
作者: Xiao N(肖努) ; Sun J(孙杰) ; Zhu HP(朱沪平) ; 津森展子 ; Chen JB(陈家碧)
通讯作者: 陈家碧
刊名: Inorg. Chim. Acta
发表日期: 2008-01-01
卷: 361, 期:11, 页:3171-3176
收录类别: SCI
部门归属: Toyama Natl Coll Technol; 上海有机所
英文摘要: Heating a benzene solution of the isomerized product of spiro[4.4]nona-1,3-diene(dicarbonyl)[ethoxy(aryl)carbene]iron phosphine adduct[(eta(3)-C9H12)Fe{C(OC2H5)(C6H4CH3-o)}(CO)(2)PPh3] (1) in a sealed quartz tube at 85-90 degrees C for 72 h gave the ring-opened eta(4) olefin-coordinated dicarbonyliron phosphine complex [Fe{eta(4)-C5H7CH=CHCH2CH=C(OC2H5)C6H4CH3-o}(CO)(2)PPh3] (3) and cyclobutane derivative [C24H22O7] (4). The thermal decomposition of analogous isomerized product [(eta(3)-C9H12)Fe{C(OC2H5)(C6H4CH3-p)}-(CO)(2)PPh3] (2) afforded the corresponding eta(4) olefin-coordinated dicarbonyliron phosphine complex [Fe{eta(4)-C5H7CH=CHCH2CH=C(OC2H5)C(6)H(4)CH(3-)p}(CO)(2)PPh3] (6) and compound 4. The structures of products 3 and 4 have been established by X- ray diffraction studies. (c) 2007 Elsevier B.V. All rights reserved.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/21425
Appears in Collections:金属有机化学国家重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2008197.pdf(319KB)----开放获取--View Download

Recommended Citation:
Xiao N,Sun J,Zhu HP,et al. Novel thermolytic products and their structures derived from thermolysis of isomerized products of spiro[4.4]nona-1,3-diene(dicarbonyl)[ethoxy(aryl) carbene]iron phosphine adducts [(eta(3)-C9H12)Fe{C(OC2H5)Ar}(CO)(2)PPh3][J]. Inorg. Chim. Acta,2008,361(11):3171-3176.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[肖努]'s Articles
[孙杰]'s Articles
[朱沪平]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[肖努]‘s Articles
[孙杰]‘s Articles
[朱沪平]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2008197.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace