中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 金属有机化学国家重点实验室  > 期刊论文
学科主题: 金属有机化学
题名: Thermolytic products derived from thermolysis of cycloolefin-coordinated diiron bridging carbene complexes
其他题名: Thermolytic products derived from thermolysis of cycloolefin-coordinated diiron bridging carbene complexes
作者: Zhang L(张磊) ; Sun J(孙杰) ; Zhu HP(朱沪平) ; 津森展子 ; Xu Q(徐强) ; Chen JB(陈家碧)
通讯作者: 陈家碧
刊名: Organometallics
发表日期: 2007
卷: 26, 期:10, 页:2630-2636
收录类别: SCI
部门归属: 上海有机所; 日本富山工业学院; 大阪产业综合研究所
英文摘要: Heating a benzene solution of the COT-coordinated diiron bridging alkoxycarbene complexes [Fe-2{mu-C(OC2H5)Ar}(CO)(4)(eta(8)-C8H8)] (1, Ar = C6H5; 2, Ar = p-CH3C6H4; 3, Ar = p-CF3C6H4) in a sealed tube at 85-90 degrees C for 72 h gave the bicycloolefin-coordinated tricarbonyliron dimers [Fe{eta(4)-C9H8(Ar}(CO)(3)](2) (10, Ar = C6H5; 12, Ar = p-CH3C6H4; 14, Ar = p-CF3C6H4) and bridging arylcarbene complexes [Fe-2{mu-C(H)Ar}(CO)(4)(eta(8)-C8H8)] (11, Ar = C6H5; 13, Ar = p-CH3C6H4; 15, Ar = p-CF3C6H4). A similar thermolysis of 7H-indene-coordinated diiron bridging alkoxycarbene complex [Fe-2{mu-C(OC2H5)C6H5}(CO)(4)(eta(4),eta(4)-C9H8)] (4) yielded the ring addition product [Fe-2{C(OC2H5)C6H5(eta(2),eta(5)-C9H8)}(CO)(5)] (16). The 7H-indene-coordinated diiron bridging arylthiocarbene complexes [Fe-2{mu-C(Ar)SC6H4CH3-p}(CO)(4)(eta(4),eta(4)-C9H8)] (8, Ar = C6H5; 9, Ar = p-C6H5C6H4) were heated similarly to afford the isomerized 7H-indene-coordinated diiron bridging carbene complexes with a mu-SC6H4CH3-p ligand, [Fe-2{mu-C(Ar)(eta(2),eta(5)-C9H8)}(mu-SC6H4CH3-p)(CO)(3)] (17, Ar = C6H5; 19, Ar = p-C6H5C6H4), and the acyliron compounds [Fe(CO)(2)(CO){C(H)Ar(eta(5)-C9H8)}] (18, Ar = C6H5; 20, Ar = p-C6H5C6H4). The structures of complexes 14, 16, 17, and 18 have been established by X-ray diffraction studies.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000246027300024
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/21419
Appears in Collections:金属有机化学国家重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2007203.pdf(187KB)----开放获取--View Download

Recommended Citation:
Zhang L,Sun J,Zhu HP,et al. Thermolytic products derived from thermolysis of cycloolefin-coordinated diiron bridging carbene complexes[J]. Organometallics,2007,26(10):2630-2636.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[张磊]'s Articles
[孙杰]'s Articles
[朱沪平]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[张磊]‘s Articles
[孙杰]‘s Articles
[朱沪平]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2007203.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace