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学科主题: 金属有机化学
题名: Unusual reactions of [{mu-(phthalazine-N-2 : N-3)}Fe-2(mu-CO)(CO)(6)] with organolithium reagents. A novel coordination mode of 1,2-diazane diiron carbonyl compounds
其他题名: 二氮杂萘羰基二铁与有机锂的新奇反应。1.2-二氮杂烷双铁羰基化合物的新奇配位模式
作者: Xiao N(肖努) ; Xu Q(徐强) ; Sun J(孙杰) ; Chen JB(陈家碧)
通讯作者: 陈家碧
刊名: Dalton Trans.
发表日期: 2006
期: 4, 页:603-608
收录类别: SCI
部门归属: 上海有机化学研究所
英文摘要: [{mu-(Phthalazine-N-2:N-3)}Fe-2(mu-CO)(CO)(6)] (1) reacts with organolithium reagents, RLi (R = CH3, C6H5, p-CH3C6H4, p-CH3OC6H4, p-CF3C6H4, p-C6H5C6H4), followed by treatment with Me3SiCl to give the novel diiron carbonyl complexes with a saturated N-N six-membered diazane ring ligand, [{C6H4CH(R)NNCH2}Fe-2(C=O)(CO)(6)] (2, R = CH3; 3, R = C6H5; 4, R = p-CH3C6H4; 5, R = p-CH3OC6H4; 6, R = p-CF3C6H4; 7, R = p-C6H5C6H4). Compounds 4 and 5 were treated with [(NH4)(2)Ce(NO3)(6)] to afford the aryl-substituted phthalazine-coordinated diiron carbonyl compounds [(mu-{1-(p-CH3C6H4)-phthalazine-N-2:N-3})Fe-2(mu-CO)(CO)(6)](8) and [(mu-{1-(p-CH3OC6H4)-phthalazine-N-2:N-3})Fe-2(mu-CO)(CO)(6)] (9), respectively. The structures of complexes 4 and 9 have been established by X-ray diffraction studies.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000234976100010
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/21411
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Xiao N,Xu Q,Sun J,et al. Unusual reactions of [{mu-(phthalazine-N-2 : N-3)}Fe-2(mu-CO)(CO)(6)] with organolithium reagents. A novel coordination mode of 1,2-diazane diiron carbonyl compounds[J]. Dalton Trans.,2006(4):603-608.
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