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学科主题: 金属有机化学
题名: Novel-N-Nucleophilic addition to and ring-breaking of coordinated cyclooctatertraene in diiron bridging carbyne complexes
其他题名: 双铁桥卡拜络合物中环辛四烯配体的新奇N-亲核加成和开环反应
作者: Zhang S(张庶) ; Xu Q(徐强) ; Sun J(孙杰) ; Chen JB(陈家碧)
通讯作者: 陈家碧
刊名: Organometallics
发表日期: 2002-01-01
卷: 21, 期:22, 页:4572-4574
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室; 日本产业技术综合研究所
英文摘要: Summary: The reactions of the diiron cationic carbyne complexes 1-3 with NaN(SiMe^3)^2 or LiN(SiMe^3)^2 in THF at low temperature give novel N-nucleophilic addition products, the neutral diiron bridging carbyne complexes 4-6, while the reactions of 1-3 with LiNEt^2 lead to breaking of the COT ring to produce the diiron bridging carbene inner salts 7-9, among which the structures of 4 and 7 have been established by X-ray diffraction studies.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/21391
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Zhang S,Xu Q,Sun J,et al. Novel-N-Nucleophilic addition to and ring-breaking of coordinated cyclooctatertraene in diiron bridging carbyne complexes[J]. Organometallics,2002,21(22):4572-4574.
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