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学科主题: 金属有机化学
题名: Synthesis of single and double butterfly iron caronyl complexes by reactions of[(μRSe)(μ-CO)Fe^2(CO)^6]anions. Crystal structures of (μp-MeC^6H^4Se)[μ-PhCH^2N(H)C=S]Fe^2(CO)^6 and [(μ-PhSe)(μ-MeAs)Fe^2(CO)^6]^2
其他题名: 通过[(μRSe)(μ-CO)Fe^2(CO)^6]阴离子的反应合成单和双蝶铁羰基络合物。(μp-MeC^6H^4Se)[μ-PhCH^2N(H)C=S]Fe^2(CO)^6 and [(μ-PhSe)(μ-MeAs)Fe^2(CO)^6]^2
作者: 宋礼诚 ; Guo-Liang Lu ; Qing-Mei Hu ; Hong-Tao Fan ; 陈家碧 ; 孙杰 ; Xiao-Ying Huang
通讯作者: 宋礼诚
刊名: J. Organomet. Chem.
发表日期: 2001-01-01
卷: 627, 页:255-262
收录类别: SCI
部门归属: 南开大学化学系; 中国科学院上海有机化学研究所金属有机化学开放实验室;
英文摘要: The in situ reactions of the [Et^3NH]+ AND [MgBr]+ salts of [(μRSe)(μ-CO)Fe^2(CO)^6] -(1) Anions with PhC(Cl)=NPh gave single butterfly complexes [(μRSe)(μ-PhC=NPhFe(CO)^6 (2, R=Ph; 3 R=p-MeC^6H^4; 4, R=Et), whereas those of the [Et^3NH]+salts of 1 with R'N=C=Safforded single butterfly complexes (μRSe)[μ-R'N(H)C=S]Fe^2(CO)^6(5,R=Ph,R'=Ph;6,R=p-MeC^6H^4R'=Ph;7R=p-MeC^6H^4,R'=PhCO;8,R=p-MeC^6H^4,R=PhCH^2). Compound 8 could also be prepared by reaction of the [MgBr]+ salt of 1 R=p-MeC^6H^4) with PhCH^2NCS followed by treatment with CF^3CO^2H. More interestingly, while the [Et^3NH]+ salt of 1 (R=Ph) reacted with Et^3OBF^4 to give a carbyne ligand-bridged single butterfly complex μ-PhSe)(μEtOC)Fe^2(CO)^6(9), reaction of the [Et^3NH]+salt of 1(R=Ph)with MeAsI^@ PRODUCED A MeAs-AsMe ligand-bridged double butterfly complex [(μ-PhSe)(μ-MeAs)Fe^2(CO)^6]^2 (10). All the new complexes, 2-10, were characterized by elemental analysis and various spectroscopic methods, for complexes 8 and 10, the structures were also confirmed by X-ray diffraction techniques.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/21379
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
宋礼诚,Guo-Liang Lu,Qing-Mei Hu,等. Synthesis of single and double butterfly iron caronyl complexes by reactions of[(μRSe)(μ-CO)Fe^2(CO)^6]anions. Crystal structures of (μp-MeC^6H^4Se)[μ-PhCH^2N(H)C=S]Fe^2(CO)^6 and [(μ-PhSe)(μ-MeAs)Fe^2(CO)^6]^2[J]. J. Organomet. Chem.,2001,627:255-262.
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