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题名: Novel reactions of cationic carbyne complexes of manganese and rhenium with (Ph=3P)=2NW(CO)=5NCO(Ph=3)=2NW(CO)=5SCN and NaW(CO)=5CN
其他题名: 锰和铼的阳离子卡拜络合物与(Ph=3P)=2NW(CO)=5NCO(Ph=3)=2NW (CO)=5SCN 和 NaW(CO)=5CN的新奇反应
作者: Tang YJ(唐拥军) ; Sun J(孙杰) ; Chen JB(陈家碧)
通讯作者: 陈家碧
刊名: Organometallics
发表日期: 1999-01-01
卷: 18, 页:2459-2465
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: The reaction of a cationic carbyne complex of manganese, [η-C=5H=5(CO)=2Mn≡CC=6H=5]BBr=4(1), with (Ph=3P)=2NW(CO)=2Mn =C(NHC=O)C=6H=5](6). The analogous reaction of a cationic carbyne complex of rhenium [η--C=5H=5(CO)2Re≡CC=6H=5]BBr=4(2), with 3 afforded the azametallacyclic complex [η-C=5H=5(CO)2ReC(C=6H=5)(C=O)NW(CO)=5](7). The reaction between 1 and (Ph=3P)=2-NW(CO)=5SCN (4) led to the loss of a sulfur atom to give the phenyl(pentacarbonylisocyanotungsten) carbene-manganese complex[η-C=5H=5(CO)2Mn=C(C=6H=5)CNW(CO)=5](8). However, the reaction of 2 with 4 afforded the (isothiocyanato) phenylcarbene-rhenium complex [η-C=5H=5(CO)=2Re=C(C=6H=5)SCN](9). Complexes 1 and 2 react with NaW(CO)=5CN(5) to produce novel phenyl(Pentacarbonylcyanotungsten)carbene-manganese and -rhenium complexes, [η-C=5H5(CO)=2Mn=C(C=6H=5)NCW(CO)=5](10). AND [η-C=5H=5(CO)=2Re=C(C=6H=5)NCW(CO)=5] (11), respectively. The structures of 6,7,8, and 11 have been established by X-ray diffreaction studies.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/21367
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Recommended Citation:
Tang YJ,Sun J,Chen JB. Novel reactions of cationic carbyne complexes of manganese and rhenium with (Ph=3P)=2NW(CO)=5NCO(Ph=3)=2NW(CO)=5SCN and NaW(CO)=5CN[J]. Organometallics,1999,18:2459-2465.
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