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学科主题: 金属有机化学
题名: Remarkable reactions of cationic carbyne complexes of manganese and rhenium with Na[Fe(CO)=4CN and Et=4N[Mn(CO)=4(CN)2]
其他题名: 锰和铼阳离子卡拜络合物与Na[Fe(CO)=4CN和Et=4N[Mn(CO)=4(CN)2]
作者: Tang YJ(唐拥军) ; Sun J(孙杰) ; Chen JB(陈家碧)
通讯作者: 陈家碧
刊名: Organometallics
发表日期: 1999-01-01
卷: 18, 页:4337-4343
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: The reaction of a cationic carbyne complex of manganese, [(η-C=5H5)(CO)=2Mn≡CC=6H=5]BBr=4(1), with Na[Fe(CO)=4CN] (3) in THF at low temperature gives the phenyl(tetracarbonylcyanoiron)carbene-manganese complex[{η-C=5H=5}(CO)=2Mn=C(C=6C=5)NCFe(CO)=4](5). The analogous reaction of a cationic carbyne complex of rhenium, [(η-C=5H=5(CO)2Re≡CC=6H=5)BBr=4(2),with 3 affords the corresponding carbene-rhenium complex[(η-C=5H=5)(CO)=2Re=C(C=6H=5)NCFe-(CO)=4](6). Complex 1 reacts with Et=4N[Mn(CO)=4(CN)=2](4) to yield the noveltrinuclear metal dicarbene-manganese complex[{(η-C=5H=5)(CO)=2Mn=C(C=6H=5)NC}=2Mn (CO)=3CN](7) and the novel tetranuclear metal dicarbene-manganese complex[{(η-C=5H=5)(CO)=2Mn =C(C=6H=5)NC}=2Mn(CO)=3CNMn(CO)2 (η-C=5H=5)] (8). Complex 2 reacts similarly with 4 to afford the corresponding trinuclear dicarbene-rhenium complex [{(η-C=5H=5)(CO)=2 Re=C(C=6H=5)NC}=2Mn-(CO)=3CN] (9). The structures of complexes 5-9 have been established by X-ray crystallography.
语种: 英语
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/21365
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Recommended Citation:
Tang YJ,Sun J,Chen JB. Remarkable reactions of cationic carbyne complexes of manganese and rhenium with Na[Fe(CO)=4CN and Et=4N[Mn(CO)=4(CN)2][J]. Organometallics,1999,18:4337-4343.
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