中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 金属有机化学国家重点实验室  > 期刊论文
学科主题: 金属有机化学
题名: Novel ring-coupled reactions of bis (cycloheptatriene)-tris(tricarbonyl iron)with aryllithium reagents
其他题名: 双(环庚三烯)三(三羰基铁)与芳基键试剂的新奇反应
作者: Zhu B(朱镔) ; Wang RT(王锐涛) ; Sun J(孙杰) ; Chen JB(陈家碧)
通讯作者: 陈家碧
刊名: J. Chem.
发表日期: 1999-01-01
卷: Dalton Trans. 1999, 页:4277-4282
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: The reactions of thebis (cycloheptatriene) tris (tricarbonyliron) , [(C=7H=8)=2F=e(CO)3]3] 1, with aryllithium reagents RC=6H=4Li(R=H, o,m-,p-CH=3O), in diethyl ether at low temperature gave acylmetalate intermediates which following alkylation with Et=3OBF=4in aqueous solution at 0℃ let to coupling of the two cycloheptatriene ligands to afford five novel isomerized(bicycloheptatriene)bis(tricarbonyliron) dicarbonyl[ethoxy(aryl)carbene]iron complexes [{(CO)=3Fe(C=7H=7)}=2(CO) =2FeC(OC=2H=5)C=6H=4R](2,R=H;3,R=oCH=3;4,R=mCH=3;5,R=pCH=3;6,R=pCH=3O)of which thestructure of 2 has been established bya single-crystal X-ray diffraction study. The reaction of complexes 2 or 5 with PPh3 Gave The Chelatedη^3allyliron phosphine adducts [{(CO)=3Fe(C=7H=7)}=2(CO)=2(PPh=3)FeC(OC=2H=5)-C=6H=4R](7,R=H;8,R=p-CH=3)
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/21363
Appears in Collections:金属有机化学国家重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
990032.pdf(638KB)----开放获取--View Download

Recommended Citation:
Zhu B,Wang RT,Sun J,et al. Novel ring-coupled reactions of bis (cycloheptatriene)-tris(tricarbonyl iron)with aryllithium reagents[J]. J. Chem.,1999,Dalton Trans. 1999:4277-4282.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[朱镔]'s Articles
[王锐涛]'s Articles
[孙杰]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[朱镔]‘s Articles
[王锐涛]‘s Articles
[孙杰]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 990032.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace