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学科主题: 氟化学
题名: Convenient synthesis of fluoroalkyl-substituted heterocycles from 1-fluoroalkyl-2-iodoalkenes
其他题名: Convenient synthesis of fluoroalkyl-substituted heterocycles from 1-fluoroalkyl-2-iodoalkenes
作者: Guan HP(关惠平) ; Tang XQ(唐小清) ; Luo BH(罗秉浩) ; Hu CM(胡昌明)
通讯作者: 胡昌明
刊名: Synthesis
发表日期: 1997
期: 12, 页:1489-1494
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所
英文摘要: A convenient synthesis of fluoroalkyl-substituted heterocycles including 3-trifluoromethylpyrazoles 7, 5-trifluoromethylisoxazoles 8 and 4-trifluoromethylpyrimidines 9 is described. This two-step sequence consists of a radical addition of fluoroalkyl iodides I to alkynes 2 to afford the corresponding alkenes 3 and condensation of 3 with hydrazine, hydroxylamine or amidines to give the aforementioned heterocycles, respectively. A possible pathway is suggested.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000071325100026
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/21337
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Guan HP,Tang XQ,Luo BH,et al. Convenient synthesis of fluoroalkyl-substituted heterocycles from 1-fluoroalkyl-2-iodoalkenes[J]. Synthesis,1997(12):1489-1494.
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