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学科主题: 金属有机化学 ; 氟化学
题名: 铁催化的苯并异吡喃鎓四氟硼酸盐的氧化自由基偶联行为研究
其他题名: Study on Iron-Catalyzed Oxidative Free Radical Dimerization of Isochromenylium Tetrafluoroborate
作者: 宋晓男 ; 莫磊 ; 胡治隆 ; 杨震宇 ; 姚祝军
通讯作者: 姚祝军
刊名: 化学学报
发表日期: 2011-01-01
卷: 69, 期:6, 页:680-686
收录类别: SCI
部门归属: 中科院上海有机化学研究所; 南京大学
英文摘要: Isochromenylium tetrafluoroborates (ICTBs) are a novel class of air- and moisture-stable organic salts recently developed by our group. These organic salts retain high reactivity of the unique isochromenylium intermediates in many chemical reactions. The dimerization of ICTBs via O-H bond oxidation with hyper-iron species in the presence of hydrogen peroxide and catalytic amount of iron complex has been studied in this work. Under the optimized conditions, two interesting dimeric products and some minor byproducts were identified, and the corresponding mechanisms were discussed.
语种: 中文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/21157
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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Recommended Citation:
宋晓男,莫磊,胡治隆,等. 铁催化的苯并异吡喃鎓四氟硼酸盐的氧化自由基偶联行为研究[J]. 化学学报,2011,69(6):680-686.
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