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学科主题: 生命有机化学
题名: Short asymmetric synthesis of (S,S)-PDP using L-prolinol derivative as economic starting material
其他题名: 使用L-脯氨酸为经济原料的(S,S)-PDP的简短不对称合成
作者: SONG XIAONAN ; Yao ZJ(姚祝军)
通讯作者: 姚祝军
刊名: Tetrahedron
发表日期: 2010
卷: 66, 期:14, 页:2589-2593
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所
英文摘要: (S,S)-PDP (5d) and its backbone (2S2'S)-bipyrioldine (1) have been extensively applied as the scaffold of various chiral ligands in catalytic asymmetric syntheses In this study, new short asymmetric syntheses of these two important C-2-symmetrical nitrogen heterocycles have been accomplished employing economically available t-prolinol derivative 10 as the starting material Excellent diastereoselectivity was achieved of the key Grignard addition to imine intermediate utilizing (S)-N-tert-butanesulfinamide as the chiral auxiliary (C) 2010 Elsevier Ltd All rights reserved
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000276371000005
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/21141
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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Recommended Citation:
SONG XIAONAN,Yao ZJ. Short asymmetric synthesis of (S,S)-PDP using L-prolinol derivative as economic starting material[J]. Tetrahedron,2010,66(14):2589-2593.
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