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学科主题: 生命有机化学
题名: Synthesis of (2R,3aR,8aR)-6-chloro-3a-hydroxy-1,2,3,3a,8,8a-hexahydropyrrolo[2,3-b]in dole-2-carboxylic acid methyl ester by reductive cyclization
其他题名: 通过还原氨化环化合成特殊的并环色氨酸衍生物
作者: Hong WX(洪文旭) ; Yao ZJ(姚祝军)
通讯作者: 姚祝军
刊名: Chin. J. Chem.
发表日期: 2004-01-01
卷: 22, 期:4, 页:365-370
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所生命有机化学国家重点实验室
英文摘要: A synthesis of (2R,3aR,8aR)-6-chloro-3a-hydroxy-1,2,3,3a,8,8a-hexahydropyrrolo[2,3-b]in dole-2-carboxylic acid methyl ester (1) was achieved. An aldol reaction with Garner aldehyde, a hydroxyl introduction by Davis reagent, and a reductive intramolecular ring-closure reaction were served as the key steps. This piece of work provides a new way to synthesize the analogues of hexahydropyrrolo[2,3-b]indole, starting from readily available chemical substrates and inexpensive reagents.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/21051
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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Recommended Citation:
Hong WX,Yao ZJ. Synthesis of (2R,3aR,8aR)-6-chloro-3a-hydroxy-1,2,3,3a,8,8a-hexahydropyrrolo[2,3-b]in dole-2-carboxylic acid methyl ester by reductive cyclization[J]. Chin. J. Chem.,2004,22(4):365-370.
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