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学科主题: 生命有机化学
题名: An efficient enantioselective synthesis of the acyl side chain of polyoxypeptins
其他题名: polyoxypeptins酰基边链的对映选择性有效合成
作者: Qin DG(秦冬光) ; Yao ZJ(姚祝军)
通讯作者: 姚祝军
刊名: Tetrahedron Lett.
发表日期: 2003-01-01
卷: 44, 期:3, 页:571-574
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所生命有机化学实验室
英文摘要: An enantioselective synthesis of theacyl side-chain 3 of polyoxypeptins 1 and 2 was achieved by the sharpless AE, with subsequent regioselective opening of the epoxyalcohol using a grignard reagent in the presence of CuI, and an aldol condensation using seebach's ester. The method reported has the advantage of a concise route and excellent enantiomeric purity, as well as starting from readily vavilable chemical substrates and the use of inexpensive reagents.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000180321100037
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/21037
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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Recommended Citation:
Qin DG,Yao ZJ. An efficient enantioselective synthesis of the acyl side chain of polyoxypeptins[J]. Tetrahedron Lett.,2003,44(3):571-574.
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