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学科主题: 物理有机化学
题名: Hydrogen-Bonded Shape-Persistent Aryl Hydrazide Polymers: Side-Chain-Tuned Formation of Vesicles and Organogels
其他题名: 氢键介质的形状受限的芳酰肼聚合物: 设计、合成及侧链调控的囊泡和有机凝胶形成
作者: Zhou C(周岑) ; Cai W(蔡伟) ; Wang GT(王贵涛) ; Li ZT(黎占亭)
通讯作者: 黎占亭
刊名: Macromol. Chem. Phys.
发表日期: 2010
卷: 211, 期:19, 页:2090-2101
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所
英文摘要: A new class of aromatic, hydrazide-based, zigzag polymer has been synthesized using the Yamazaki polymerization conditions. Hydrophobic, hydrophilic or amphiphilic side chains are introduced to the backbones to tune their solubility in organic solvents of different polarities. The side chains form successive, intramolecular, six-membered RO center dot center dot center dot HN hydrogen bonds, which increase the planarity of the backbones. The new shape-persistent polymers are revealed to self-assemble into vesicles or fibers to gelate organic solvents of different polarities. The polymeric backbones may be regarded as a conceptual extension of the emerging foldamers, which are usually constructed from oligomeric backbones.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000283023600004
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/20879
Appears in Collections:物理有机化学研究室_期刊论文

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Recommended Citation:
Zhou C,Cai W,Wang GT,et al. Hydrogen-Bonded Shape-Persistent Aryl Hydrazide Polymers: Side-Chain-Tuned Formation of Vesicles and Organogels[J]. Macromol. Chem. Phys.,2010,211(19):2090-2101.
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